Water Purification Emplyoing Nanocomposites: Mechanism and Fabrication Strategies

Authors

  • Harsh Bhardwaj Assistant Professor, Department of Chemistry, Shri RK Patni Girls College, Kishangarh, Ajmer, Rajasthan, India
  • Sapna Meena Assistant Professor, Department of Chemistry, SMBM Govt Girls College, Nagaur, Rajasthan, India
  • Meenakshi Yadav Associate Professor, Department of Chemistry, Meerut College, Meerut, Uttar Pradesh, India
  • Ashok Kakodia Professor, Department of Chemistry, Government College, Rajgarh, Alwar, Rajasthan, India
  • Lalit Mohan Assistant Professor, Department of Zoology, Dayalbagh Educational Institute, Agra, Uttar Pradesh, India
  • Anil Kumar Assistant Professor, Department of Physics, Bangur Govt College, Didwana, Didwana Kuchaman, Rajasthan, India
  • Mahendra Vyas Assistant Professor, Department of Chemistry, Govt Engineering College, Bikaner, Rajasthan, India
  • Magan Prasad Former Professor, Department of Chemistry, MSJ Govt PG College, Bharatpur, Rajasthan, India
  • Suresh K Verma Professor, Department of Chemistry, Govt Girls College, Chomu, Jaipur, Rajasthan, India
  • Raaz K Maheshwari Freelance Investigator and Scientific Writer, Jaipur, India; Former Professor, Department of Chemistry, MDSU-SBRM Govt PG College, Nagaur, Rajasthan, India

DOI:

https://doi.org/10.59436/jsiane.v6i1.05.2583-2093

Keywords:

Porous ceramic nanotubes, nanostructured materials, surface engineering, advanced synthesis, water purification, adsorption and catalysis, functional nanocomposites, membrane technology, structure–property relationships, environmental applications

Abstract

Porous ceramic nanocomposites offer a combination of properties that most polymeric membranes cannot match: thermal and chemical durability from the ceramic matrix, and surface-level tunability from the nanoscale fillers. This review covers the fabrication strategies, purification mechanisms, and practical applications of these materials. Ceramic systems based on alumina, zirconia, silica, and titania are examined alongside nanofillers including carbon nanotubes, graphene oxide, metal oxides, and metal-organic frameworks (MOFs). Fabrication routes from conventional sintering and sol-gel processing through to electrospinning, atomic layer deposition, and additive manufacturing are assessed for their effect on pore architecture, surface chemistry, and transport behaviour. The purification mechanisms covered are adsorption, size-based sieving, photocatalytic degradation, and antimicrobial activity, including where these work together in nanocomposite systems. Performance across permeability, selectivity, fouling resistance, and chemical stability is compared against polymeric and monolithic ceramic membranes using laboratory, pilot, and commercial data. Applications in municipal and industrial wastewater treatment, desalination, oil-water separation, and decentralised systems are reviewed. Challenges that remain unresolved include fabrication cost, nanoparticle leaching, long-term durability, and regulatory compliance. Open research questions centre on green synthesis, stimuli-responsive designs, digital manufacturing, and integration with broader treatment systems.

References

Ağtaş, M., Yılmaz, Ö., Dilaver, M., Alp, K., & Koyuncu, İ. (2020). Hot water recovery and reuse in the textile sector with a pilot-scale ceramic ultrafiltration/nanofiltration membrane system. Journal of Cleaner Production, 256, 120359. https://doi.org/10.1016/j.jclepro.2020.120359

Al Harby, N. F., El-Batouti, M., & Elewa, M. M. (2022). Prospects of Polymeric Nanocomposite Membranes for Water Purification and Scalability and their Health and Environmental Impacts: A Review. Nanomaterials, 12(20), 3637. https://doi.org/10.3390/nano12203637

Almasri, D., Yehia Manawi, Makki, S., Nafia Tasneem, Simson, S., Iman Abdel-Hadi, Agcaoili, J., Lawler, J., & Viktor Kochkodan. (2025). A novel, low-cost clay ceramic membrane for the separation of oil-water emulsions. Scientific Reports, 15(1). https://doi.org/10.1038/s41598-025-99143-0

Ang, W. J., Yeit Haan Teow, Chang, Z. H., Mohammad, A. W., & Wan, T. W. (2024). Innovative ceramic membrane plate filtration system for sustainable semiconductor industry wastewater treatment: A pilot scale study. Chemical Engineering Journal, 496, 153767–153767. https://doi.org/10.1016/j.cej.2024.153767

Arumugham, T., Kaleekkal, N. J., Gopal, S., Nambikkattu, J., K, R., Aboulella, A. M., Ranil Wickramasinghe, S., & Banat, F. (2021). Recent developments in porous ceramic membranes for wastewater treatment and desalination: A review. Journal of Environmental Management, 293, 112925. https://doi.org/10.1016/j.jenvman.2021.112925

Bahadi, S. A., Q.A. Drmosh, & Onaizi, S. A. (2024). Adsorptive removal of organic pollutants from aqueous solutions using novel GO/bentonite/MgFeAl-LTH nanocomposite. Environmental Research, 248, 118218–118218. https://doi.org/10.1016/j.envres.2024.118218

Barbaros, I., Yang, Y., Safaei, B., Yang, Z., Qin, Z., & Asmael, M. (2022). State-of-the-art review of fabrication, application, and mechanical properties of functionally graded porous nanocomposite materials. Nanotechnology Reviews, 11(1), 321–371. https://doi.org/10.1515/ntrev-2022-0017

Chen, Y., Wang, N., Ola, O., Xia, Y., & Zhu, Y. (2021). Porous ceramics: Light in weight but heavy in energy and environment technologies. Materials Science and Engineering: R: Reports, 143, 100589. https://doi.org/10.1016/j.mser.2020.100589

Chin Ho Kirk, Douglas, Y., Wang, X., Sun, J., Zhao, Q., & Wang, J. (2024). Nanofiltration Ceramic Membranes as a Feasible Two‐Pronged Approach toward Desalination and Lithium Recovery. Global Challenges, 8(2). https://doi.org/10.1002/gch2.202300151

Coelho, L. L., Di Luccio, M., Hotza, D., de Fátima Peralta Muniz Moreira, R., Moreira, A. C., Fernandes, C. P., Rezwan, K., & Wilhelm, M. (2021). Tailoring asymmetric Al2O3 membranes by combining tape casting and phase inversion. Journal of Membrane Science, 623, 119056. https://doi.org/10.1016/j.memsci.2021.119056

Dehkordi, M. M., Hedayatikhah, S., Haghmohammadi, M., Baramkohi, M. A., Montazeri, A., & Aghababai Beni, A. (2025). Design and fabrication of nano-composite ceramic membranes for the adsorption of antibiotics from pharmaceutical wastewater. RSC Advances, 15(13), 10227–10242. https://doi.org/10.1039/d5ra00414d

Ding, Z., Zhang, J., Xia, Z., Xin, B., Yu, J., & Lei, X. (2025). BiOBr@PZT Nanocomposite Membranes via Electrospinning-SILAR Technology: A Sustainable Green Material for Photocatalytic Degradation in Coloration-Related Wastewater Remediation. Sustainability, 17(11), 4984. https://doi.org/10.3390/su17114984

Dommati, H., Sinha Ray, S., Wang, J.-C., & Chen, S.-S. (2019). A comprehensive review of recent developments in 3D printing technique for ceramic membrane fabrication for water purification. RSC Advances, 9(29), 16869–16883. https://doi.org/10.1039/C9RA00872A

Eszter Bódis, Kolos Molnár, János Móczó, & Zoltán Károly. (2022). Preparation and Characterization of Fibrous Alumina and Zirconia Toughened Alumina Ceramics with Gradient Porosity. Nanomaterials, 12(23), 4165–4165. https://doi.org/10.3390/nano12234165

Ewis, D., Norhan Ashraf Ismail, Hafiz, M., Abdelbaki Benamor, & Hawari, A. H. (2021). Nanoparticles functionalized ceramic membranes: fabrication, surface modification, and performance. Environmental Science and Pollution Research, 28(10), 12256–12281. https://doi.org/10.1007/s11356-020-11847-0

Eya Kacem, Suk, H. D., Deepalekshmi Ponnamma, Hassan, M. K., Hawari, A., Alshammari, B. A., & Al‐Ejji, M. (2025). Exploring 3D Printing and Electrospinning Technologies for Advanced Porous Membrane Fabrication: A Review. Advanced Materials Technologies, 10(17). https://doi.org/10.1002/admt.20240200

Fu, W., Tang, T., Chen, X., Yang, Y., Mi, B., Yang, K., Xu, X., & Zhang, X. (2023). Nano-ceramic membranes combined with ozonation for water treatment: Fundamentals and engineering applications. Journal of Hazardous Materials Advances, 10, 100279. https://doi.org/10.1016/j.hazadv.2023.100279

Gao, N., Wang, L., Hu, X., & Liu, H. (2023). Mussel-inspired in-situ metallization of nano-Ag on ceramic membrane for catalytic degradation of dye wastewater. Journal of Alloys and Compounds, 955, 170191. https://doi.org/10.1016/j.jallcom.2023.170191

Ghassan Abukhanafer, Tiwari, A., Kishor Kumar S, Eswari Beeram, M. Mariappan, Dixit, P. R., & Bhavsar, S. N. (2025). Photocatalytic degradation of organic pollutants in water: Application of TiO2-based nanocomposites. Periodicals of Engineering and Natural Sciences (PEN), 13(2), 403–416. https://doi.org/10.21533/pen.v13.i2.263

Gu, Q., Tze Pin Ng, Bao, Y., How Yong Ng, Tan, S. T., & Wang, J. (2022). Developing better ceramic membranes for water and wastewater Treatment: Where microstructure integrates with chemistry and functionalities. Chemical Engineering Journal, 428, 130456–130456. https://doi.org/10.1016/j.cej.2021.130456

He, Z., Wang, N., Yang, X., Mu, L., Wang, Z., Su, J., Luo, M., Li, J., Deng, F., & Lan, X. (2023). Antifouling induced by surface wettability of poly(dimethyl siloxane) and its nanocomposites. Nanotechnology Reviews, 12(1). https://doi.org/10.1515/ntrev-2022-0552

Hussein, M. A., Shahzad, H. K., Patel, F., Atieh, M. A., Al-Aqeeli, N., Baroud, T. N., & Laoui, T. (2020). Porous Al2O3-CNT Nanocomposite Membrane Produced by Spark Plasma Sintering with Tailored Microstructure and Properties for Water Treatment. Nanomaterials, 10(5), 845. https://doi.org/10.3390/nano10050845

Jarvis, P., Carra, I., Jafari, M., & Judd, S. J. (2022). Ceramic vs polymeric membrane implementation for potable water treatment. Water Research, 215, 118269. https://doi.org/10.1016/j.watres.2022.118269

Kolya, H., & Kang, C.-W. (2023). Next-Generation Water Treatment: Exploring the Potential of Biopolymer-Based Nanocomposites in Adsorption and Membrane Filtration. Polymers, 15(16), 3421. https://doi.org/10.3390/polym15163421

Li, C., Sun, W., Lu, Z., Ao, X., & Li, S. (2020). Ceramic nanocomposite membranes and membrane fouling: A review. Water Research, 175, 115674. https://doi.org/10.1016/j.watres.2020.115674

Li, P., Li, Y.-X., Wu, Y.-Z., Xu, Z.-L., Zhang, H.-Z., Gao, P., & Xu, S.-J. (2021). Thin-film nanocomposite NF membrane with GO on macroporous hollow fiber ceramic substrate for efficient heavy metals removal. Environmental Research, 197, 111040. https://doi.org/10.1016/j.envres.2021.111040

Li, Y., Wang, X., Ren, L., Dai, R., Qiu, Z., Zhou, H., & Wang, Z. (2025). Membrane modification strategies for virus removal from water. IScience, 28(3), 111944. https://doi.org/10.1016/j.isci.2025.111944

Lu, D., Zhuang, L., Yang, Y., Jia, S., Su, L., Zhang, P., Qin, Y., Niu, M., Peng, K., & Wang, H. (2025). Strong and Tough Porous Silicon Carbide Ceramics. ACS Nano, 19(19), 18313–18321. https://doi.org/10.1021/acsnano.5c00570

Ma, D., Li, H., Meng, Z., Zhang, C., Zhou, J., Xia, J., & Wang, Y. (2021). Absolute and Fast Removal of Viruses and Bacteria from Water by Spraying-Assembled Carbon-Nanotube Membranes. Environmental Science & Technology, 55(22), 15206–15214. https://doi.org/10.1021/acs.est.1c04644

Ma, J., He, C., Hua, K., Yan, J., Cai, M., & Rong, H. (2024). Fabrication and application of highly permeable ceramic membranes: Membrane-forming mechanism, pore structure, separation performance and fouling mechanism analyses. Separation and Purification Technology, 356, 129866. https://doi.org/10.1016/j.seppur.2024.129866

Mansour Alhoshan, Shukla, A. K., Mana, T. H., Ali, A., & Alam, J. (2022). An Evolving MOF Thin-Film Nanocomposite Tubular Ceramic Membrane for Desalination Pretreatment. Journal of Inorganic and Organometallic Polymers and Materials, 33(2), 337–352. https://doi.org/10.1007/s10904-022-02501-y

Masashi Kotobuki, Gu, Q., Zhang, L., & Wang, J. (2021). Ceramic-Polymer Composite Membranes for Water and Wastewater Treatment: Bridging the Big Gap between Ceramics and Polymers. Molecules, 26(11), 3331–3331. https://doi.org/10.3390/molecules26113331

Motta Cabrera, S., Winnubst, L., Richter, H., Voigt, I., & Nijmeijer, A. (2021). Industrial application of ceramic nanofiltration membranes for water treatment in oil sands mines. Separation and Purification Technology, 256, 117821. https://doi.org/10.1016/j.seppur.2020.117821

Moyo, W., Nhamo Chaukura, Motsa, M. M., Titus, Mamba, B. B., Sebastiaan G. J. Heijman, & Thabo T. I. Nkambule. (2022). Modeling the antifouling properties of atomic layer deposition surface-modified ceramic nanofiltration membranes. Biofouling, 38(5), 441–454. https://doi.org/10.1080/08927014.2022.2084613

Naclerio, A. E., Cheng, P., Hus, S. M., Diulus, J. T., Checa, M., Vlassiouk, I., Fissell, W. H., Coupin, M., Warner, J., Collins, L., Kolmakov, A., Li, A.-P., & Kidambi, P. R. (2025). Scalable Bottom-Up Synthesis of Nanoporous Hexagonal Boron Nitride (h-BN) for Large-Area Atomically Thin Ceramic Membranes. Nano Letters, 25(8), 3221–3232. https://doi.org/10.1021/acs.nanolett.4c05939

Putu Doddy Sutrisna, Khoiruddin Khoiruddin, Pra Cipta W.B. Mustika, Suryadi Ismadji, & I Gede Wenten. (2024). ADVANCEMENTS IN CERAMIC MEMBRANES FOR ROBUST OIL-WATER SEPARATION. Journal of Environmental Chemical Engineering, 12(5), 113658–113658. https://doi.org/10.1016/j.jece.2024.113658

Qiu, Q., Gao, M., Shao, C., Sun, S., Liu, Y., & Zhang, H. (2023). Copper Nanoparticles Coupled with Fine-Powdered Active Carbon-Modified Ceramic Membranes for Improved Filtration Performance in a Membrane Bioreactor. Water, 15(23), 4141–4141. https://doi.org/10.3390/w15234141

Rasouli, Y., Maltais-Tariant, R., Barbeau, B., Peldszus, S., Boudoux, C., & Claveau-Mallet, D. (2024). Performance of biological ion exchange resin and gravity-driven ceramic membrane hybrid process for surface water treatment. Separation and Purification Technology, 332, 125769. https://doi.org/10.1016/j.seppur.2023.125769

Sahu, A., Dosi, R., Kwiatkowski, C., Schmal, S., & Poler, J. C. (2023). Advanced Polymeric Nanocomposite Membranes for Water and Wastewater Treatment: A Comprehensive Review. Polymers, 15(3), 540. https://doi.org/10.3390/polym15030540

Satyam, S., & Patra, S. (2024). Innovations and challenges in adsorption-based wastewater remediation: A comprehensive review. Heliyon, 10(9), e29573. https://doi.org/10.1016/j.heliyon.2024.e29573

Soltani, R., Marjani, A., & Shirazian, S. (2020). A hierarchical LDH/MOF nanocomposite: single, simultaneous and consecutive adsorption of a reactive dye and Cr(vi). Dalton Transactions, 49(16), 5323–5335. https://doi.org/10.1039/d0dt00680g

Sondhi, H., Chen, M., Michiel Pieter Nijboer, Arian Nijmeijer, Roozeboom, F., Mikhael Bechelany, Alexey Kovalgin, & Mieke Luiten-Olieman. (2025). Ceramic Nanofiltration Membranes: Creating Nanopores by Calcination of Atmospheric-Pressure Molecular Layer Deposition Grown Titanicone Layers. Membranes, 15(3), 86–86. https://doi.org/10.3390/membranes15030086

Spoială, A., Ilie, C.-I., Ficai, D., Ficai, A., & Andronescu, E. (2021). Chitosan-Based Nanocomposite Polymeric Membranes for Water Purification—A Review. Materials, 14(9), 2091. https://doi.org/10.3390/ma14092091

Sun, K., Lyu, Q., Zheng, X., Liu, R., Tang, C. Y., Zhao, M., & Dong, Y. (2024). Enhanced water treatment performance of ceramic-based forward osmosis membranes via MOF interlayer. Water Research, 254, 121395–121395. https://doi.org/10.1016/j.watres.2024.121395

Thawanrat Kobkeatthawin, Suwilai Chaveanghong, Jirawat Trakulmututa, Taweechai Amornsakchai, Puangrat Kajitvichyanukul, & Siwaporn Meejoo Smith. (2022). Photocatalytic Activity of TiO2/g-C3N4 Nanocomposites for Removal of Monochlorophenols from Water. Nanomaterials, 12(16), 2852–2852. https://doi.org/10.3390/nano12162852

Tripathy, J., Mishra, A., Pandey, M., Thakur, R. R., Chand, S., Rout, P. R., & Shahid, M. K. (2024). Advances in Nanoparticles and Nanocomposites for Water and Wastewater Treatment: A Review. Water, 16(11), 1481. https://doi.org/10.3390/w16111481

Wang, C., Park, M. J., Yu, H., Matsuyama, H., Drioli, E., & Shon, H. K. (2022). Recent advances of nanocomposite membranes using layer-by-layer assembly. Journal of Membrane Science, 661, 120926. https://doi.org/10.1016/j.memsci.2022.120926

Wang, S., Xia, H., Mi, J., Wu, M., Yang, S., Xu, R., Li, X., Zhu, L., Xu, M., & Dong, Y. (2024). Fabrication of high-performance recrystallized silicon carbide ceramic membrane based on particle packing optimization. Journal of Membrane Science, 705, 122922–122922. https://doi.org/10.1016/j.memsci.2024.122922

Xie, X., Wang, L., Wei, J., He, H., Guo, Z., Wang, C., Wen, X., & Song, Y. (2024). Progress in ceramic membrane coupling ozonation process for water and wastewater treatment: A critical review. Chemical Engineering Journal, 493, 152475. https://doi.org/10.1016/j.cej.2024.152475

Xu, D., Luo, X., Jin, P., Zhu, J., Zhang, X., Zheng, J., Yang, L., Zhu, X., Liang, H., & Van der Bruggen, B. (2022). A novel ceramic-based thin-film composite nanofiltration membrane with enhanced performance and regeneration potential. Water Research, 215, 118264. https://doi.org/10.1016/j.watres.2022.118264

Yan, P., Pu, Z., Du, M., Ge, X., Dong, J., Wang, H., Li, J., & Cui, Z. (2024). Preparation of ceramic membranes with small pore size, narrow pore size distribution and investigation of oil-water separation mechanism. Journal of Membrane Science, 716, 123522. https://doi.org/10.1016/j.memsci.2024.123522

Yang, Z., Li, L., Jiang, C., Zhao, N., Zhang, S., Guo, Y., Chen, Y., Xue, S., Ji, C., Zhao, S., Gonzales, R. R., Matsuyama, H., Xia, J., & Niu, Q. J. (2021). Tailored thin film nanocomposite membrane incorporated with Noria for simultaneously overcoming the permeability-selectivity trade-off and the membrane fouling in nanofiltration process. Journal of Membrane Science, 640, 119863–119863. https://doi.org/10.1016/j.memsci.2021.119863

Ye, Y., Du, Y., Hu, T., You, J., Bao, B., Wang, Y., & Wang, T. (2021). 3D Printing of Integrated Ceramic Membranes by the DLP Method. Industrial & Engineering Chemistry Research, 60(26), 9368–9377. https://doi.org/10.1021/acs.iecr.1c02224

Yu, L., Kanezashi, M., Nagasawa, H., & Tsuru, T. (2020). Phase inversion/sintering-induced porous ceramic microsheet membranes for high-quality separation of oily wastewater. Journal of Membrane Science, 595, 117477. https://doi.org/10.1016/j.memsci.2019.117477

Yuan, K., Chen, R., & Zeng, Y. (2025). Fabrication of Composite Membrane by Constructing Helical Carbon Nanotubes in Ceramic Support Channels for Efficient Emulsion Separation. Membranes, 15(5), 150–150. https://doi.org/10.3390/membranes15050150

Zhang, M., Ning, H., Shang, J., Liu, F., & Peng, S. (2023). A robust superhydrophobic-superoleophilic PDMS/Al2O3/CM composite ceramic membrane: Stability, efficient emulsified oil/water separation, and anti-pollution performance. Separation and Purification Technology, 328, 124864. https://doi.org/10.1016/j.seppur.2023.124864

Zhang, S., Yuan, J., Wang, S., Li, Y., Xu, Y., Sun, D., Liu, F., & Cheng, G. J. (2023). Synergistic Multilevel Sieving Membranes: Integrating Cellular Graphene Skeleton with Continuous MOFs Nanolayer for Superior Multiphase Water Separation. Advanced Functional Materials, 34(8). https://doi.org/10.1002/adfm.202307571

Zhang, W., Ou, J., Wang, B., Wang, H., He, Q., Song, J., Zhang, H., Tang, M., Zhou, L., Gao, Y., & Sun, S. (2021). Efficient heavy metal removal from water by alginate-based porous nanocomposite hydrogels: The enhanced removal mechanism and influencing factor insight. Journal of Hazardous Materials, 418, 126358. https://doi.org/10.1016/j.jhazmat.2021.126358

Zhang, Y., Tan, Y., Sun, R., & Zhang, W. (2023). Preparation of Ceramic Membranes and Their Application in Wastewater and Water Treatment. Water, 15(19), 3344. https://doi.org/10.3390/w15193344

Zou, D., & Fan, Y. (2021). State-of-the-art developments in fabricating ceramic membranes with low energy consumption. Ceramics International, 47(11), 14966–14987. https://doi.org/10.1016/j.ceramint.2021.02.195

Published

2026-03-10

How to Cite

Water Purification Emplyoing Nanocomposites: Mechanism and Fabrication Strategies. (2026). Journal of Science Innovations and Nature of Earth, 6(1), 20-33. https://doi.org/10.59436/jsiane.v6i1.05.2583-2093

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